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Thursday 9 May 2013

Nomenclature of Alkynes

Alkynes can be named both in IUPAC and trivial methods. Here's the nomenclature of alkynes.

The systematic name of an alkyne is obtained by replacing the “ane” ending of the alkane name with “yne.” Analogous to the way compounds with other functional groups are named, the longest continuous chain containing the carbon–carbon triple bond is numbered in the direction that gives the alkyne functional group suffix as low a number as possible. If the triple bond is at the end of the chain, the alkyne is classified as a terminal alkyne. Alkynes with triple bonds located elsewhere along the chain are called nternal alkynes. For example, 1-butyne is a terminal alkyne, whereas 2-pentyne is an internal alkyne.

In common nomenclature, alkynes are named as substituted acetylenes. The common name is obtained by citing the names of the alkyl groups, in alphabetical order, that have replaced the hydrogens of acetylene. Acetylene is an unfortunate common name for the smallest alkyne because its “ene” ending is characteristic of a double bond rather than a triple bond. If the same number for the alkyne functional group suffix is obtained counting from either direction along the carbon chain, the correct systematic name is the one that contains the lowest substituent number. If the compound contains more than one substituent, the substituents are listed in alphabetical order.


Ditulis Oleh : Unknown // 04:19
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